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The dataset is comprised of analyses of sediment cores and sediment trap samples from ferruginous and meromictic Brownie Lake, Minnesota, U.S.A from January 2018 through February 2021. The dataset includes bulk sediment characteristics including water content, grain size, major and minor elements. Voltammetric scans were collected on porewaters and lake waters. Sediment porewaters were analyzed for pH, total alkalinity, ferrous iron, and dissolved sulfur species contents. Sediment samples were maintained under the exclusion of oxygen for analysis by synchrotron-based X-ray absorption spectroscopy. 

Depth profiles of water column chemical and physical properties were assessed with seasonal-scale frequency from two meromictic lakes in the upper Midwest, U.S.A. from 2015 to 2019. Brownie Lake in Minneapolis, MN and Canyon Lake in the Huron Mountains of MI both contain elevated hypolimnetic dissolved iron (i.e. “ferruginous”). Several parameters were routinely measured with deployable probes at meter or sub-meter resolution at the deepest location in each lake. Water samples were also collected for laboratory analysis. 

Uranium isotopes (²³⁸U/²³⁵U) have been used widely over the last decade as a global proxy for marine redox conditions. The largest isotopic fractionations in the system occur during U reduction, removal, and burial. Applying this basic framework, global U isotope mass balance models have been used to predict the extent of ocean floor anoxia during key intervals throughout Earth's history. However, there are currently minimal constraints on the isotopic fractionation that occurs during reduction and burial in anoxic and iron‐rich (ferruginous) aquatic systems, despite the consensus that ferruginous conditions are thought to have been widespread through the majority of our planet's history. Here we provide the first exploration of δ²³⁸U values in natural ferruginous settings. We measured δ²³⁸U in sediments from two modern ferruginous lakes (Brownie Lake and Lake Pavin), the water column of Brownie Lake, and sedimentary rocks from the Silurian‐Devonian boundary that were deposited under ferruginous conditions. Additionally, we provide new δ²³⁸U data from core top sediments from anoxic but nonsulfidic settings in the Peru Margin oxygen minimum zone. We find that δ²³⁸U values from sediments deposited in all of these localities are highly variable but on average are indistinguishable from adjacent oxic sediments. This forces a reevaluation of the global U isotope mass balance and how U isotope values are used to reconstruct the evolution of the marine redox landscape.